[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2 N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
نویسندگان
چکیده
In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O'-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa-hedron surrounding the methanol-coordinated metal atom. The methanol mol-ecule forms an O-H⋯N hydrogen bond to an N atom of the 4,4'-bipyridine solvent mol-ecule; the hy-droxy group of the Schiff base forms an O-H⋯N hydrogen bond to the other N atom of another mol-ecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis.
منابع مشابه
Aqua[N′-(3-ethoxy-2-oxidobenzyl-κO)furan-1-carbohydrazidato-κ2 N′,O]dioxidomolybdenum(VI)–4,4′-bipyridine (2/1)
The Mo(VI) atom in the title co-crystal, [Mo(C(14)H(12)N(2)O(4))O(2)(H(2)O)]·0.5C(10)H(8)N(2), is O,N,O'-chelated by the deprotonated Schiff base and coordinated by the oxide and water O atoms in an octa-hedral geometry. The five-membered chelate ring is planar (r.m.s. deviation = 0.019 Å), but the six-membered chelate ring is puckered (r.m.s. deviation = 0.108 Å). Two mononuclear mol-ecules ar...
متن کاملcatena-Poly[[bis(2,4-dichlorobenzoato)bis(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′]
In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa-hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro-benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4'-bipyridine ligands. The bipyridine ligands also lies on a two...
متن کاملTrichlorido(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)(methanol-κO)indium(III) methanol monosolvate
In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol mol-ecule and three Cl atoms. In the crystal, inter-molecular O-H⋯O and O-H⋯Cl hydrogen bonds link the complex and solvent methanol mol-ecules. Intra-molecular C...
متن کامل[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2 N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
In the title mol-ecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N'-(3,5-diiodo-2-oxidobenzyl-idene-κO)-4-methyl-benzo-hydra-zidate (L) ligand, one oxide O atom, one methano-late [V-O = 1.761 (3) Å] and one methanol [V-O = 2.383 (4) Å] O atom in a distorted octa-hedral geometry. In the L ligand, the two benzene rings are nearly...
متن کاملcis-(Dimethyl sulfoxide-κO)[N′-(3-ethoxy-2-oxidobenzylidene-κO)-2-hydroxybenzohydrazidato-κ2 N′,O]dioxidomolybdenum(VI)
The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octa-hedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O a...
متن کامل